Andrew Garfield Peter Parker / Spider-Man Emma Stone Gwen Stacy Jamie Foxx Max Dillon / Electro Dane DeHaan Harry Osborn / Green Goblin Colm Feore Donald Menken Felicity Jones Felicia Hardy Paul Giamatti Aleksei Sytsevich / The Rhino Sally Field Aunt May Embeth Davidtz Mary Parker Campbell Scott Richard Parker Marton Csokas Dr. Ashley Kafka Louis Cancelmi Man in Black Suit Max Charles Young Peter Parker B.J. Novak Allistar Smythe Sarah Gadon Kari Michael Massee Gustav Fiers (The Gentleman) Jorge Vega Jorge Bill Heck G-5 Co-Pilot Teddy Coluca Gwen's Cabbie Helen Stern British Desk Attendant Aidy Bryant Statue of Liberty Lady Cal McCrystal Principal Conway Anslem Richardson Times Square Cop Mark Doherty SWAT Team Leader James Colby Lead Officer Kari Coleman Helen Stacy Skyler Gisondo Howard Stacy Charlie DePew Philip Stacy Robert Newman Police Captain Adrian Martinez Bodega Cashier Thaddeus Phillips Robber James McCauley Air Traffic Controller Rachael McOwen Dispatcher David Shabtai Dispatcher Greg Connolly Osborn Butler Timothy Adams Pilot Tug Coker Pilot Jabari Gray Pilot Jamie Lynn Concepcion Jorge's Mother Pat Kiernan NY1 News Anchor Clem Cheung Chinese Grandpa Andrei Runtso Armed Robber Slate Holmgren Ravencroft Guard Dario Barosso Bully Paul Urcioli Doctor David Shih Doctor Daniel Gerroll OsCorp Department Head Jonathan Braylock Times Square Bystander Steven Hauck Corporate Lawyer J.D. Walsh Dr. Jallings, Science Investigator Stan Lee Graduation Guest Jessica Shea Alverson Graduation Parent (uncredited) Stefanie Barry Times Square driver (uncredited) Chris Cooper Norman Osborn (uncredited) BJ Davis NYPD Officer (uncredited) Julia Davis NYPD Officer (uncredited) Frank Deal Agent Berkley (uncredited) Odette Warder Henderson Pedestrian (uncredited) Denis Leary Captain Stacy (uncredited) Martin Sheen Uncle Ben (uncredited)